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Gold catalysts for pure hydrogen production in the …

The production of hydrogen containing very low levels of carbon monoxide for use in polymer electrolyte fuel cells requires the development of catalysts that show very high activity at low temperatures where the equilibrium for the removal of carbon monoxide using the water–gas shift reaction is favourable. It has been claimed that oxide-supported gold …

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What is the effect of Sn and Mo oxides on gold catalysts …

A foam-like mesoporous silica (MCF)-supported gold (Au) nanoparticle (NP) catalyst was prepared by a facile one-pot synthesis strategy. SnO x and MoO x were introduced as promoters by a wet impregnation method to synthesize promoted catalysts Au–SnO x /MCF and Au–MoO x /MCF, respectively. The evaluation of the prepared …

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A spinel-alumina inert oxide supported gold catalyst with high Au dispersion and excellent CO oxidation activity was developed by a deposition–precipitation method. The activation atmosphere could tune the reaction pathway by adjusting the amount of surface adsorbed water species, thus transforming the reaction intermediates from HCO …

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Water–gas shift on gold catalysts: catalyst systems and …

Since the pioneering finding by Haruta et al. that small gold nanoparticles on reducible supports can be highly active for low-temperature CO oxidation, the synthesis, characterization, and application of supported gold catalysts have attracted much attention. The water –gas shift reaction (WGSR: CO + H 2 O = CO 2 + H 2) is important for …

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Supported gold catalysts for the total oxidation of alkanes …

The variation of the propane conversion with the reaction temperature for gold-containing catalysts is shown in Fig. 4.Although the Au/MnO x catalyst gave very high catalytic activity and complete alkane conversion took place at 300 °C, Au/CoO x was found to be the most active catalyst and complete combustion of propane was readily achieved …

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Defective Mesocrystal ZnO-Supported Gold Catalysts: …

We present a strategy to prepare a highly active Au/ZnO catalyst for CO oxidation by introducing abundant Zn- and O-vacancy defects into a ZnO support of mesocrystal form. Two different ZnO supports were chosen for comparison; almost defect-free ZnO nanorods (NR-ZnO) and twin-brush-like ZnO mesocrystals (TB-ZnO) with rich …

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